JEE Main & Advanced Sample Paper JEE Main Sample Paper-27

  • question_answer
    Ketones are less reactive than aldehydes because

    A)  the + I-effect of the alkyl groups increases the electron deficiency of the carbonyl carbon

    B)  the + I-effect of the alkyl groups decreases the electron deficiency of the carbonyl carbon

    C)  of steric hindrance to the attacking nucleophile

    D) both (b) and (c) options are correct

    Correct Answer: D

    Solution :

    Nucleophilic attack can be faster at carbon containing more partial (+) charge (more electrophilic centre) and less steric crowding. Rate of Nucleophilic addition reaction \[\propto {{\delta }^{+}}\] at C = 0 group.             \[C=O\,\propto \,{{\delta }^{+}}\propto \,\frac{1}{steric\,hinderance\,at\,C=O\,group}\]


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