JEE Main & Advanced Sample Paper JEE Main Sample Paper-33

  • question_answer
    The non-stoichiometric compound \[F{{e}_{094}}O\] is formed when x% of \[F{{e}^{2+}}\] ions are replaced by \[F{{e}^{3+}}\]ions, then x is:

    A)  18     

    B)                                     15

    C)  12         

    D)                     6

    Correct Answer: A

    Solution :

    According to charge balance, number of \[F{{e}^{3+}}\] ions replacing x \[F{{e}^{+2}}\] ions is equal to \[\frac{2x}{3}\] \[\therefore \]    Vacancies of cations \[\,\,=x-\frac{2x}{3}=\frac{x}{3}\] But       \[\frac{x}{3}=1-0.94\,=0.06\]             \[x=0.06\,\times 3=0.18\]       or 18% Sol.69   \[C{{H}_{3}}C{{H}_{2}}COOH\xrightarrow[P]{C{{l}_{2}}}C{{H}_{3}}\underset{\begin{smallmatrix}  | \\  OH \end{smallmatrix}}{\mathop{CH}}\,-COOH\]             \[\xrightarrow{KOH(alc.)}\,C{{H}_{2}}\,=CHCOOH\]


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