JEE Main & Advanced Sample Paper JEE Main Sample Paper-8

  • question_answer
    What is the EMF of represented cell at 298 \[Ag|A{{g}^{+}}(aq\,0.1\,M)|\,\,|{{H}^{+}}(aq,\,0.1M),\]\[{{H}_{2}}(g,\,0.1\,\,bar)|Pt\] Given: \[E_{Ag/A{{g}^{+}}}^{0}=-0.8\,V\]

    A)  0.77V                   

    B)  -0.829V

    C)  -0.77V                 

    D)  None of these

    Correct Answer: C

    Solution :

     Cell reaction is \[2Ag(s)+2{{H}^{+}}(aq)\to 2A{{g}^{+}}(aq)+{{H}_{2}}(g)\] \[{{E}_{cell}}=-0.80-\frac{0.0591}{2}\log \frac{{{(0.1)}^{2}}\times 0.1}{{{(0.1)}^{2}}}\] \[{{E}_{cell}}=-0.80+0.02955=-0.77\text{V}\]


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