JEE Main & Advanced Sample Paper JEE Main Sample Paper-9

  • question_answer
    Among the following, the strongest base is

    A) \[{{C}_{6}}{{H}_{5}}N{{H}_{2}}\]                               

    B) \[p-N{{O}_{2}}{{C}_{6}}{{H}_{4}}N{{H}_{2}}\]

    C) \[m-N{{O}_{2}}-{{C}_{6}}{{H}_{4}}N{{H}_{2}}\]

    D) \[{{C}_{6}}{{H}_{5}}C{{H}_{2}}N{{H}_{2}}\]

    Correct Answer: D

    Solution :

    Lone pair is not taking pair in resonance, most basic. In other cases, lone pair of nitrogen is part of delocalization which decreases Lewis base strength.


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