A) \[C{{H}_{3}}-C{{H}_{2}}-\underset{\underset{O}{\mathop{\parallel }}\,}{\mathop{C}}\,-H\]
B) \[C{{H}_{3}}-\overset{\overset{O}{\mathop{\parallel }}\,}{\mathop{CH}}\,-C{{H}_{3}}\]
C)
D) \[C{{H}_{3}}-\overset{\overset{C{{H}_{3}}}{\mathop{|}}\,}{\mathop{CH}}\,-\underset{\underset{O}{\mathop{\parallel }}\,}{\mathop{C}}\,-H\]
Correct Answer: D
Solution :
For Cannizaro reaction, \[\alpha \] hydrogen must absent | |
[a] | [b] |
[c] | [d] \[C{{H}_{3}}-\overset{\overset{CH}{\mathop{|}}\,}{\mathop{CH}}\,-\underset{\underset{O}{\mathop{\parallel }}\,}{\mathop{C}}\,-H\] |
It is a special case which can give Cannizaro reaction although contain \[\alpha -H\] |
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