KVPY Sample Paper KVPY Stream-SX Model Paper-20

  • question_answer
    Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1M is \[100\Omega \]. The conductivity of this solution is\[1.29 S {{m}^{-1}}\]. Resistance of the same cell when filled with 0.02 M of the same solution is \[520\Omega \].  The molar conductivity of 0.02 M solution of electrolyte will be

    A) \[1.24\times {{10}^{-4}}S\,{{m}^{2}}mo{{l}^{-1}}\]

    B) \[12.4\times {{10}^{-4}}S\,{{m}^{2}}mo{{l}^{-1}}\]

    C) \[124\times {{10}^{-4}}S\,{{m}^{2}}mo{{l}^{-1}}\]

    D) \[1240\times {{10}^{-4}}S\,{{m}^{2}}mo{{l}^{-1}}\]

    Correct Answer: A

    Solution :

    Conductivity \[(\kappa )=\frac{l}{R.a.}\]
    When. \[\operatorname{R}=100\Omega \]and \[\kappa =1.29\operatorname{S}\,{{m}^{-1}}\]
    Cell constant. \[\left( \frac{l}{a} \right)=1.29\times 100=129\]
    Now conductivity of 0.02 M solution
    When \[R=520\Omega \] will be
    \[\kappa =\frac{1}{520}\times 129;\,{{\Lambda }_{m}}=\frac{\kappa \times 1000}{M}\]\[=\frac{129}{520}\times \frac{1000}{0.02}=1.24\times {{10}^{-4}}\operatorname{S}\,{{m}^{2}}{{\operatorname{mol}}^{-1}}\]


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