KVPY Sample Paper KVPY Stream-SX Model Paper-27

  • question_answer
    Assuming the formation of an ideal solution, determine the boiling point of a mixture containing 1560 g benzene (molar mass = 78) and 1125 g chlorobenzene (molar mass = 112.54) using the following against an external pressure of 1000 Torr.

    A) \[90{}^\circ C\]

    B) \[100{}^\circ C\]

    C) \[110{}^\circ \]

    D) \[120{}^\circ C\]

    Correct Answer: B

    Solution :

    \[20\,\,\text{mole}\,{{C}_{6}}{{H}_{6}},\]\[10\,\,\text{mole}\,{{C}_{6}}{{H}_{5}}Cl\] \[\Rightarrow \]\[{{X}_{B}}=\frac{2}{3},\] \[{{X}_{C}}=\frac{1}{3}\]
    at \[t=100{}^\circ C\] \[\Rightarrow \]\[{{p}_{s}}=300\times \frac{1}{3}+1350\times \frac{2}{3}=100\]\[+900\,(=1000)\]


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