NEET Sample Paper NEET Sample Test Paper-25

  • question_answer
    A solution of urea (molar mass 56) boils at \[{{100.18}^{o}}C\,\,\text{at}\]atmospheric pressure. If \[{{K}_{f}}\]and \[{{K}_{b}}\]for water are 1.86 and 0.512 K \[molalit{{y}^{-1}}\]respectively, the above solution will freeze at

    A) \[-{{6.54}^{o}}C\]

    B)  \[{{6.54}^{o}}C\]

    C) \[-{{0.654}^{o}}C\]

    D)  \[{{0.654}^{o}}C\]

    Correct Answer: C

    Solution :

     \[\frac{\Delta {{\Tau }_{b}}}{\Delta {{T}_{f}}}=\frac{{{K}_{b}}}{{{K}_{f}}}\] \[\therefore \] \[\Delta {{\Tau }_{f}}=\frac{{{K}_{f}}}{{{K}_{b}}}\times \Delta {{T}_{b}}=\frac{1.86}{0.512}\times 0.18=0.654\] \[\therefore \]\[f.pt.=0-0.654=-0.654{{\,}^{o}}C\]


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