NEET Sample Paper NEET Sample Test Paper-66

  • question_answer
    van?t Hoff factor of \[BaC{{l}_{2}}\] of cone. 0.10 M is 1.98. Percentage dissociation of \[BaC{{l}_{2}}\] on this conc. will be

    A) 49                                

    B) 69           

    C) 89                                

    D) 98            

    Correct Answer: A

    Solution :

         \[BaC{{l}_{2}}\,\,\rightleftharpoons \,\,B{{a}^{2+}}\,+\,\,2C{{l}^{-}}\] \[\begin{matrix}    Initially  \\    After\,\,dissociation  \\ \end{matrix}\,\,\,\,\,\,\,\,\begin{matrix}    1  \\    1\alpha   \\ \end{matrix}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{matrix}    0  \\    \alpha   \\ \end{matrix}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\begin{matrix}    0  \\    2\alpha   \\ \end{matrix}\] \[Total=1-\alpha +\alpha +2\alpha =1+2\alpha \] \[\alpha \,=\,\,\frac{1.98-1}{\alpha }\,\,=\,\,\frac{0.98}{\alpha }\,\,\,=\,\,0.49\,\] for a mole \[\alpha = 0.49\] For 0.01 mole \[\alpha \,\,=\, \frac{0.49}{0.01}\,\,=\,\,49\]


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