NEET Sample Paper NEET Sample Test Paper-81

  • question_answer
    In solid\[N{{H}_{3}}\], each \[N{{H}_{3}}\] molecule had 6 other \[N{{H}_{3}}\] molecules as nearest neighbours. \[\Delta H\] of sublimation of \[N{{H}_{3}}\] at the melting point is 30.8 kJ/mole and the estimated AH of sublimation in the absence of hydrogen bonding is 14.4 kJ/mole. the strength of H-bond in solid \[N{{H}_{3}}\] is

    A)  \[5.5 kJ mo{{l}^{-}}^{1}\]                

    B)  \[16.4 kJ mo{{l}^{-}}^{1}\]

    C)  \[2.7 kJ mo{{l}^{-}}^{1}\]                

    D)  \[-8.7 kJ mo{{l}^{-}}^{1}\]

    Correct Answer: C

    Solution :

    Energy for 6 hydrogen bond \[= \,30.4-14.4\] \[=\,\,\,16.4\,\,kJ\,\,mo{{l}^{-}}^{1}\] Thus, strength of one-hydrogen bond will be \[\frac{16.4}{6}=2.7\,\,kJ\,\,mol\]


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