NEET Sample Paper NEET Sample Test Paper-81

  • question_answer
    Which of the following option show correct numeric value of osmotic pressure at a given temperature T K. pH of 0.1 M monobasic acid is measured to be 2?

    A)  0.1 RT             

    B)  0.11 RT

    C)  1.1 RT             

    D)  0.01 RT

    Correct Answer: B

    Solution :

    Dissociation of acid occurs as \[\operatorname{HA} \,\,{{H}^{+}}\,+{{A}^{-}}\] Initially,             c              0      0 At equilibrium, \[c-c\,\alpha \]        \[c\alpha \]   \[c\,\alpha \] \[[{{H}^{+}}]=c\,\alpha \] \[{{10}^{-\,2}}=c\,\alpha \] \[\alpha =\frac{{{10}^{-\,2}}}{c}=\frac{{{10}^{-\,2}}}{0.1}\] \[=\,\,\,{{10}^{-\,1}}=0.1\] We know that \[\alpha =\frac{i-1}{n-1}\,\,\,\Rightarrow \,0.1=\frac{i-1}{2-1}\] \[i=1.1\] \[\pi =i\,cRT\] \[\pi =1.1\times 0.1\times RT\,\,=\,\,0.11\,\,RT\]


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