NEET Sample Paper NEET Sample Test Paper-82

  • question_answer
    Calculate the limiting molar conductivity of NaBr. If limiting molar conductivities of NaCl, KBr and KCl are 126, 152 and \[150 s c{{m}^{2}}\,mo{{l}^{-\,1}}\]respectively.

    A)  \[128.5 s c{{m}^{2}}\,mo{{l}^{-\,1}}\]         

    B)  \[248 s c{{m}^{2}}\,mo{{l}^{-\,1}}\]

    C)  \[328 s c{{m}^{2}}\,mo{{l}^{-\,1}}\]            

    D)  \[348 s c{{m}^{2}}\,mo{{l}^{-\,1}}\]

    Correct Answer: A

    Solution :

    \[\Lambda _{NaCl}^{\infty }\,\,=\,\,\Lambda _{N{{a}^{+}}}^{\infty }\,\,+\,\,\Lambda _{C{{l}^{-}}}^{\infty }\,\,(126\,s\,\,c{{m}^{2}}\,mo{{l}^{-\,1}})\]    ? (i) \[\Lambda _{KBr}^{\infty }\,\,=\,\,\Lambda _{{{K}^{+}}}^{\infty }\,\Lambda _{B{{r}^{-}}}^{\infty }\,\,(150\,s\,\,c{{m}^{2}}\,mo{{l}^{-\,1}})\]                ? (ii) \[\Lambda _{KCl}^{\infty }\,\,=\,\,\Lambda _{{{K}^{+}}}^{\infty }+\,\Lambda _{C{{l}^{-}}}^{\infty }\,\,(150\,s\,\,c{{m}^{2}}\,mo{{l}^{-\,1}})\]    ? (iii) Eqs. \[\left( i \right)+\left( ii \right)-\left( iii \right)\] \[\Lambda _{NaBr}^{\infty }\,\,=\,\,\Lambda _{N{{a}^{+}}}^{\infty }+\,\Lambda _{B{{r}^{-}}}^{\infty }\] \[=\,\,126+152-150=128\,\,s\,\,c{{m}^{2}}\,mo{{l}^{-\,1}}\]


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