JEE Main & Advanced Chemistry Equilibrium / साम्यावस्था Sample Paper Topic Test - Ionic Equilibrium

  • question_answer
    Silver ions are added to solution with \[[B{{r}^{-}}]=[C{{l}^{-}}]=[CO_{3}^{2-}]=[AsO_{4}^{3-}]=0.1\,M\]. Which compound will precipitate at lowest  \[[A{{g}^{+}}]\]?

    A) \[AgBr({{K}_{sp}}=5\times {{10}^{-13}})\]

    B) \[AgCl({{K}_{sp}}=1.8\times {{10}^{-10}})\]

    C) \[A{{g}_{2}}C{{O}_{3}}({{K}_{sp}}=8\times {{10}^{-12}})\]

    D) \[A{{g}_{3}}As{{O}_{4}}({{K}_{sp}}={{10}^{-22}})\]

    Correct Answer: A

    Solution :

    [a] \[[A{{g}^{+}}]\] required for precipitation of various salts are
    \[AgBr=7.07\times {{10}^{-8}},AgCl=1.3\times {{10}^{-5}};\]
    \[A{{g}_{2}}C{{O}_{3}}=1.26\times {{10}^{-4}};A{{g}_{3}}As{{O}_{4}}=1.38\times {{10}^{-6}}\]


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