JEE Main & Advanced Chemistry Solutions / विलयन Sample Paper Topic Test - Solutions

  • question_answer
    A 0.001 molal solution of \[\left[ Pt{{\left( N{{H}_{3}} \right)}_{4}}C{{l}_{4}} \right]\] in water had a freezing point depression of\[0.0054{}^\circ C\]. If \[{{K}_{f}}\] for water is 1.80, the correct formulation for the above molecule is:

    A) \[\left[ Pt{{\left( N{{H}_{3}} \right)}_{4}}C{{l}_{3}} \right]Cl\]   

    B) \[\left[ Pt{{\left( N{{H}_{3}} \right)}_{4}}Cl \right]C{{l}_{2}}\]

    C) \[\left[ Pt{{\left( N{{H}_{3}} \right)}_{4}}C{{l}_{2}} \right]C{{l}_{3}}\]          

    D) \[\left[ Pt{{\left( N{{H}_{3}} \right)}_{4}}C{{l}_{4}} \right]\]

    Correct Answer: B

    Solution :

    [b] \[\Delta {{T}_{f}}=im{{K}_{f}};\,0.0054=i\times 1.8\times 0.001\] \[i=3.\] So it is \[\left[ Pt{{\left( N{{H}_{3}} \right)}_{4}}Cl \right]C{{l}_{2}}\].


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