JEE Main & Advanced Chemistry Solutions / विलयन Sample Paper Topic Test - Solutions

  • question_answer
    The expression relating degree of dissociation of the weak electrolyte \[{{A}_{x}}{{B}_{y}}\] with its van't Hoff factor is

    A) \[\alpha =\frac{i-1}{x+y-1}\]

    B) \[\alpha =\frac{i+1}{x+y-1}\]

    C) \[\alpha =\frac{x+y-1}{i-1}\]

    D) \[\alpha =\frac{x+y-1}{i+1}\]

    Correct Answer: A

    Solution :

    [a] \[\underset{1-\alpha }{\mathop{{{A}_{\times }}{{B}_{y}}}}\,\underset{\alpha x}{\mathop{x{{A}^{y+}}}}\,+\underset{\alpha y}{\mathop{y{{B}^{x-}}}}\,\]
    Total amount of species \[=1+(x+y-1)\alpha \]
    Van't Hoff factor, \[i=\frac{1+(x+y-1)\alpha }{1}\]
    or         \[\alpha =\frac{i-1}{x+y-1}\]


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