AFMC AFMC Solved Paper-2001

  • question_answer
    4.6 kJ heat is liberated on burning 0.5 g of sulphur. The enthalpy of formation of \[S{{O}_{2}}\] is: [molecular weight of S = 32, O = 16]

    A) + 294.4 kJ            

    B) - 294.4 kJ

    C) + 462.4 kJ            

    D) - 462.4 kJ

    Correct Answer: B

    Solution :

    Sulphur bums in oxygen according to the following equation \[\underset{32g}{\mathop{S}}\,+{{O}_{2}}\xrightarrow{{}}S{{O}_{2}}+\Delta {{h}_{f}}\] 0.5 g S liberate = 4.6 kJ heat 1 g S liberate \[=\frac{4.6}{0.5}kJ\] 32 g s will liberate \[=\frac{4.6}{0.5}\times 32=294.4kJ\] Heat of formation is the amount of heat liberated or absorbed when one mole of compound is formed from its constituent elements hence, Heat of formation of \[S{{O}_{2}}=-294.4\,kJ\]


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