AFMC AFMC Solved Paper-2004

  • question_answer
    Which of the following can't be used in Friedel- Crafts' reactions?

    A) \[FeC{{l}_{3}}\]                                

    B) \[FeB{{r}_{2}}\]

    C) \[AlC{{l}_{3}}\]                                 

    D) \[NaCl\]

    Correct Answer: D

    Solution :

    Friedel-Craft's reaction: This reaction is used for alkylation or acylation of benzene and  is initiated by electrophilic attack on benzene. Electrophile is produced in the presence of any Lewis acid \[viz\,AlC{{l}_{3}}\,FeC{{l}_{3}},\,FeB{{r}_{3}}\]etc. \[\text{NaCl}\]is not a Lewis acid hence, cannot be used. Electrohile is generated as follows \[C{{H}_{3}}Cl+AlC{{l}_{3}}\xrightarrow{{}}AlCl_{4}^{-}+\underset{\begin{smallmatrix}  (Carbocation\, \\  E{{l}^{+}}) \end{smallmatrix}}{\mathop{^{+}C{{H}_{3}}}}\,\]


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