AFMC AFMC Solved Paper-2011

  • question_answer
    Dehydration of alcohol is an example of which type of reaction?

    A) Substitution      

    B) Elimination

    C) Addition              

    D) Rearrangement

    Correct Answer: B

    Solution :

    Dehydration of alcohol involves the loss of two atoms or groups from the adjacent carbon atoms, hence it is an example of \[\beta -\] elimination reaction. \[\underset{\text{ethanol}}{\mathop{\overset{\beta }{\mathop{C}}\,{{H}_{3}}\overset{\alpha }{\mathop{C}}\,{{H}_{2}}OH}}\,\xrightarrow{+{{H}^{+}}}\overset{\beta }{\mathop{C}}\,{{H}_{3}}\overset{\alpha }{\mathop{C}}\,{{H}_{2}}\overset{+}{\mathop{O}}\,{{H}_{2}}\xrightarrow[-{{H}_{2}}O]{}\]     \[\overset{\beta }{\mathop{C}}\,{{H}_{3}}\overset{\alpha }{\mathop{C}}\,H_{2}^{+}\xrightarrow[-{{H}^{+}}]{}\underset{\text{ehene}}{\mathop{\overset{\beta }{\mathop{C}}\,{{H}_{2}}}}\,=\overset{\alpha }{\mathop{C}}\,{{H}_{2}}\]


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