JEE Main & Advanced AIEEE Solved Paper-2002

  • question_answer
    Acetylene does not react with AIEEE  Solved  Paper-2002

    A) Na          

    B)                           ammoniacal \[AgN{{O}_{3}}\]

    C) \[HCl\]                    

    D)           \[NaOH\]

    Correct Answer: D

    Solution :

    \[CH\equiv CH+Na\xrightarrow{{}}CH\equiv {{C}^{-}}N{{a}^{+}}+\frac{1}{2}{{H}_{2}}\]              \[CH\equiv CH+\] ammoniacal \[AgN{{O}_{3}}\xrightarrow{{}}\]                                 \[CH\equiv {{C}^{-}}A{{g}^{+}}+\underset{\text{White ppt}}{\mathop{HN{{O}_{3}}}}\,\]              \[CH\equiv CH+HCl\xrightarrow{{}}C{{H}_{2}}=CH-Cl\]              usually occurs in the presence of \[H{{g}^{2+}}\].              \[CH\equiv CH+NaOH\xrightarrow{{}}\] no reaction              Because of hard acid hard base soft acid soft base (HASB) theory              \[CH\equiv CH+NaN{{H}_{2}}\xrightarrow{{}}CH\equiv {{C}^{-}}N{{a}^{+}}\]feasible.


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