JEE Main & Advanced AIEEE Solved Paper-2002

  • question_answer
    Which of the following ions has the maximum magnetic moment?   AIEEE  Solved  Paper-2002

    A) \[M{{n}^{2+}}\]                  

    B) \[F{{e}^{2+}}\]    

    C)           \[T{{i}^{2+}}\]      

    D)           \[C{{r}^{2+}}\]

    Correct Answer: A

    Solution :

    Magnetic moment depends upon the number of unpaired electron. Higher the number of unpaired electron in the given ion, higher will be its magnetic moment.              \[\mu =\sqrt{n(n+2)}\]              where \[n=\] number of unpaired electron              \[_{25}Mn=[Ar]4{{s}^{2}},3{{d}^{5}}\]              \[M{{n}^{2+}}[Ar]3{{d}^{5}},4{{s}^{o}}\]              Number of unpaired electrons \[=5\]              \[_{26}Fe=[Ar]4{{s}^{2}},3{{d}^{6}}\]              \[F{{e}^{2+}}=[Ar]3{{d}^{6}},4{{s}^{o}}\]                           Number of unpaired electrons \[=4\]              \[_{22}Ti=[Ar]4{{s}^{2}},\,3{{d}^{2}}\]              \[T{{i}^{2+}}=[Ar]3{{d}^{2}},4{{s}^{0}}\]                           Number of unpaired electrons \[=2\]              \[_{24}Cr=[Ar]3{{d}^{5}},4{{s}^{1}}\]              \[C{{r}^{2+}}=[Ar]3{{d}^{4}},4{{s}^{0}}\]                                        \[\therefore \,M{{n}^{2+}}\] has five unpaired electron and hence the dipole moment \[(\mu =n\sqrt{n+2})\] will be maximum for manganese.


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