JEE Main & Advanced AIEEE Solved Paper-2002

  • question_answer
    In a mixture of A and B, components show negative deviation when   AIEEE  Solved  Paper-2002

    A) A-B interaction is stronger than A-A and B-B interaction

    B) A-B interaction is weaker than A-A and B-B interaction             

    C) \[\Delta {{V}_{\operatorname{mi}x}}>0\],  \[\Delta {{S}_{\operatorname{mi}x}}>0\]

    D) \[\Delta {{V}_{\operatorname{mi}x}}=0\], \[\Delta {{S}_{\operatorname{mi}x}}>0\]

    Correct Answer: A

    Solution :

    Negative deviation means lower vapour pressure, it suggests high boiling point, thus resultant intermolecular force should be stronger than individual one.


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