AIIMS AIIMS Solved Paper-1999

  • question_answer
    Which of the following is the correct statement for \[P{{H}_{3}}\]?

    A)  it is less poisonous than \[N{{H}_{3}}\]

    B)  it is less basic than \[N{{H}_{3}}\]

    C)  electronegativity of  \[P{{H}_{3}}\]is >\[N{{H}_{3}}\]

    D)  it does not show reducing properties.

    Correct Answer: B

    Solution :

    Nitrogen is more electronegative than the phosphorus atom. In \[N{{H}_{3}}\], nitrogen attracts the bonded pair of electron between N and H atoms towards it, and this effect is more in \[N{{H}_{3}}\] than in \[P{{H}_{3}}\]. Due to this effect, the lone pair of electrons in \[N{{H}_{3}}\] can participate more than that of \[P{{H}_{3}}\].


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