AIIMS AIIMS Solved Paper-2007

  • question_answer
    Which of the following does not exist as a Zwitter ion?

    A)  Glycine

    B)  Glutamic acid

    C)  Sulphanilic acid                       

    D)  p-aminobenzoic acid

    Correct Answer: D

    Solution :

    \[o-\] and p - aminobenzoic acids do not exist as a Zwitter ion. The lone pair of electrons on the \[-N{{H}_{2}}\] group is donated towards the benzene ring due to resonance effect. As a result, acidic character of \[-COOH\] group and basic character of \[-N{{H}_{2}}\] group decrease. Therefore, the weakly acidic \[-COOH\] group cannot transfer a \[{{H}^{+}}\] ion to the weakly basic \[-N{{H}_{2}}\] group. Thus o-or p-aminobenzoic acids do not exist as Zwitter ion.


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