AIIMS AIIMS Solved Paper-2009

  • question_answer
    The solubility product of a salt having formula \[4.85\text{ }g/cc\] is \[\begin{matrix}    A(g)  \\    2  \\    \underset{=x}{\mathop{(2-3x)}}\,  \\ \end{matrix}+\begin{matrix}    B(g)  \\    2  \\    \underset{=x}{\mathop{(2-3x)}}\,  \\ \end{matrix}\begin{matrix}    C(g)  \\    0  \\    3x  \\ \end{matrix}+\begin{matrix}    D(g)  \\    0  \\    3x  \\ \end{matrix}\begin{matrix}   (initially)  \\   (at\,equilibrium)  \\ \end{matrix}\] the solubility of an another salt having formula \[\Rightarrow \] is twice the molar solubility of \[2-3x=x\], the solubility product o \[\therefore \] is

    A) \[x=\frac{1}{2}\]       

    B) \[{{K}_{P}}=\frac{{{p}_{C}}.p{{  }_{D}}}{{{p}_{A}}.{{p}_{B}}}\]  

    C) \[=\frac{{{\left( \frac{3x}{V} \right)}^{2}}}{{{\left( \frac{2-3x}{V} \right)}^{2}}}\]    

    D) \[=\frac{9\times {{\left( \frac{1}{2} \right)}^{2}}}{4-12\times \frac{1}{2}+9\times {{\left( \frac{1}{2} \right)}^{2}}}\]

    Correct Answer: A

    Solution :

    \[Fe{{C}_{2}}{{O}_{4}}\] (where, 5 = solubility) \[C{{r}_{2}}O_{7}^{2-}\] \[\therefore \] or \[=\frac{1}{2}=0.5\] \[C{{r}_{2}}O_{7}^{2-}\]   \[3U{{O}^{2+}}+C{{r}_{2}}O_{7}^{2-}+8{{H}^{+}}\xrightarrow{{}}3UO_{2}^{2+}\] For \[+2C{{r}^{3+}}+4{{H}_{2}}O\] \[{{D}_{2}}O\] \[{{H}_{2}}O\] \[N<O<S<Cl\]\[Al\] [\[Ga\] Solubility of \[_{13}Al=[Ne]3{{s}^{2}}3{{p}^{1}}\] solubility of \[_{31}Ga=[Ar]3{{d}^{10}},4{{s}^{2}}4{{p}^{1}}\]] \[Al.\]


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