NEET AIPMT SOLVED PAPER MAINS 2012

  • question_answer
    The catalytic activity of transition metals and their compounds is ascribed mainly to

    A)  their magnetic behaviour

    B)  their unfilled d-orbitals

    C)  their ability to adopt variable oxidation states

    D)  their chemical reactivity

    Correct Answer: C

    Solution :

    Transition metals show variable oxidation states, due to which they can perform as catalyst.                 e.g.,       \[2S{{O}_{2}}+{{O}_{2}}\xrightarrow[(catalyst)]{{{V}_{2}}{{O}_{5}}}2S{{O}_{3}}\]                 \[S{{O}_{2}}+{{\overset{+5}{\mathop{V}}\,}_{2}}{{O}_{5}}\xrightarrow{{}}S{{O}_{3}}+{{\overset{+4}{\mathop{V}}\,}_{2}}{{O}_{4}}\] \[{{\overset{+4}{\mathop{V}}\,}_{2}}{{O}_{4}}+{{O}_{2}}\xrightarrow{{}}{{\overset{+5}{\mathop{V}}\,}_{2}}{{O}_{5}}\]


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