NEET AIPMT SOLVED PAPER SCREENING 2010

  • question_answer
    Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy ?

    A) \[CaS{{O}_{4}}\]              

    B) \[BeS{{O}_{4}}\]                                       

    C) \[BaS{{O}_{4}}\]              

    D)        \[SrS{{O}_{4}}\]

    Correct Answer: B

    Solution :

    Key Idea Hydration energy varies inversely with size and in sulphates of alkaline earth metals lattice energy remains almost constant. The order of size of alkaline earth metals is                 \[B{{e}^{2+}}<C{{a}^{2+}}<S{{r}^{2+}}<B{{a}^{2+}}\] Thus, the order of hydration energy is                 \[B{{e}^{2+}}>C{{a}^{2+}}>S{{r}^{2+}}>B{{a}^{2+}}\] Hence, \[BeS{{O}_{4}}\]has the hydration enthalpy higher than the lattice enthalpy.


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