NEET AIPMT SOLVED PAPER SCREENING 2011

  • question_answer
    If the \[{{\text{E}}^{\text{o}}}_{\text{cell}}\]for a given reaction has a negative value then which of the following gives the correct relationships for the values of \[{{\text{G}}^{\text{o}}}\] and \[{{\text{K}}_{\text{eq}}}\]?

    A) \[\Delta {{\text{G}}^{\text{o}}}\text{}\,\text{0;}\,{{\text{K}}_{\text{eq}}}>1\]

    B)        \[\Delta {{\text{G}}^{\text{o}}}\text{}\,\text{0;}\,{{\text{K}}_{\text{eq}}}<1\]

    C)        \[\Delta {{\text{G}}^{\text{o}}}>\,\text{0;}\,{{\text{K}}_{\text{eq}}}<1\]

    D)        \[\Delta {{\text{G}}^{\text{o}}}>\,\text{0;}\,{{\text{K}}_{\text{eq}}}>1\]

    Correct Answer: C

    Solution :

    \[\Delta {{G}^{o}}=-nF{{E}^{o}}\]When \[{{E}^{o}}\] is negative, then \[\Delta {{E}^{o}}>0\]\[\Delta {{G}^{o}}=-RT\ln {{K}_{eq}}\]When  \[\Delta {{G}^{o}}>0,{{K}_{eq}}={{10}^{-x}}\]which is less, than one, ie,\[{{K}_{eq}}<1.\]


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