NEET AIPMT SOLVED PAPER SCREENING 2012

  • question_answer
    In which of the following compounds, nitrogen exhibits highest oxidation state?

    A) \[{{\text{N}}_{\text{2}}}{{\text{H}}_{\text{4}}}\]

    B)                        \[\text{N}{{\text{H}}_{3}}\]       

    C)        \[{{\text{N}}_{\text{3}}}\text{H}\]                         

    D)        \[\text{N}{{\text{H}}_{\text{2}}}\text{OH}\]

    Correct Answer: C

    Solution :

    Let the oxidation state of nitrogen in the given compounds be x. \[{{\overset{x}{\mathop{N}}\,}_{2}}{{\overset{x1}{\mathop{H}}\,}_{4}}\]                 \[2(x)+(+1)4=0\]                 \[2x=-4\] \[\therefore \]  \[x=-2\] \[\overset{x}{\mathop{N}}\,{{\overset{+1}{\mathop{H}}\,}_{3}}\]                 \[x+(+1)3=0\] \[\therefore \]  \[x=-3\]                \[{{\overset{x}{\mathop{N}}\,}_{3}}\overset{+1}{\mathop{H}}\,\]                 \[(x)3+(+1)=0\]                                 \[3x=-1\] \[\therefore \]  \[x=-\frac{1}{3}\] \[\overset{x}{\mathop{N}}\,\overset{+1}{\mathop{{{H}_{2}}}}\,\overset{-2+1}{\mathop{OH}}\,\]                 \[x+(+1)2+(-2)+(+1)=0\]                                 \[x+2-2+1=0\]                                 \[x+1=0\]                                 \[x=-1\] Thus, oxidation state of nitrogen is highest in\[{{N}_{3}}H.\]


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