AMU Medical AMU Solved Paper-1998

  • question_answer
    Which is correct increasing order of their tendency to from\[{{M}^{3-}}\]ion?

    A)  \[Bi>Sb>As>P>N\]  

    B)  \[Bi<Sb<As<P<N\]

    C)  \[N<P<Sb<Bi<As\]  

    D)  \[Bi>Sb\tilde{\ }N\tilde{\ }P>As\]

    Correct Answer: B

    Solution :

    : On moving down the group, the stability of \[-3\]oxidation state decreases. This is due to the following reasons (i) On descending a group the size of the atom or ion increases with the result attraction of the nucleus per newly added electron decreases (ii) A large anion connot fit easily into lattice of a small cation, (iii) As the negative charge on the ion increases, it becomes more and more susceptible to polarisation.


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