AMU Medical AMU Solved Paper-2001

  • question_answer
    Identify the reaction not feasible among the following

    A)  \[2NaOH\xrightarrow{\Delta }N{{a}_{2}}O+{{H}_{2}}O\]

    B)  \[2LiOH\xrightarrow{\Delta }L{{i}_{2}}O+{{H}_{2}}O\]

    C)  \[MgC{{O}_{3}}\xrightarrow{\Delta }MgO+C{{O}_{2}}\]

    D)  All of the above

    Correct Answer: A

    Solution :

                     Key Idea The thermal stability of group I hydroxides increases with increasing size of cation. \[LiOH\] decomposes readily but other alkali hydroxides are most stable.  \[2NaOH\xrightarrow{\Delta }N{{a}_{2}}O+{{H}_{2}}O\] This reaction is not feasible because sodium hydroxide is thermally stable.  \[2LiOH\xrightarrow{\Delta }L{{i}_{2}}O+{{H}_{2}}O\] \[LiOH\] is unstable towards heating due to small size of Li atom.  \[MgC{{O}_{3}}\] gives magnesium oxide and \[C{{O}_{2}}\] on heating.                 \[MgC{{O}_{3}}\xrightarrow{\Delta }MgO+C{{O}_{2}}\]


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