AMU Medical AMU Solved Paper-2004

  • question_answer
    When chlorine is passed through concentrated solution of KOH, the compound formed is

    A)  \[KlC{{O}_{4}}\]                              

    B)  \[KlC{{O}_{3}}\]

    C)  \[KlC{{O}_{2}}\]                              

    D)  \[KlCO\]

    Correct Answer: B

    Solution :

                     When chlorine is passed through hot concentrated solution of KOH, potassium chlorate is formed.                 \[3\,C{{l}_{2}}+\underset{\begin{smallmatrix}  hot, \\  cone. \end{smallmatrix}}{\mathop{6KOH}}\,\xrightarrow{{}}5KCl+\,\,\,\underset{\begin{smallmatrix}  potassium \\  chlorate \end{smallmatrix}}{\mathop{KCl{{O}_{3}}}}\,\,\,+3{{H}_{2}}O\] Note - When chlorine ne is passed into cold dilute solution of KOH, potassium hypochlorite is formed. \[C{{l}_{2}}+2KOH\xrightarrow{{}}KCl+\,\,\,\underset{\begin{smallmatrix}  potassium \\  hypochlorite \end{smallmatrix}}{\mathop{KClO}}\,\,\,\,+{{H}_{2}}O\]


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