AMU Medical AMU Solved Paper-2004

  • question_answer
    The equilibrium constant Kp for the reaction, \[{{H}_{2}}(g)+{{I}_{2}}(g)2HI(g)\] is

    A)  more than one                

    B)  less than one

    C)  equal to \[{{K}_{c}}\]                    

    D)  zero

    Correct Answer: C

    Solution :

                                    Key Idea The relation between \[{{K}_{p}}\] and \[{{K}_{c}}\] is given by                                                 \[{{K}_{p}}={{K}_{c}}{{(RT)}^{\Delta {{n}_{g}}}}\] where \[\Delta \,{{n}_{(g)}}\] number of moles of products - number of moles of reactants For the following equation                 \[{{H}_{2}}(g)+{{I}_{2}}(g)2HI(g)\]                                 \[\Delta {{n}_{g}}=2-2=0\]                                 \[{{K}_{p}}={{K}_{c}}\,{{(RT)}^{0}}\]                                 \[{{K}_{p}}={{K}_{c}}\] Note - Fore the reaction                 \[{{n}_{1}}A+{{n}_{2}}B{{m}_{1}}C+{{m}_{2}}D\] the following cases are possible 1. When \[({{m}_{1}}+{{m}_{2}})>({{n}_{1}}+{{n}_{2}})\] eg,          \[PC{{l}_{5}}PC{{l}_{3}}+C{{l}_{2}}\] then                      \[{{K}_{p}}>{{K}_{c}}\] 2. When \[({{m}_{1}}+{{m}_{2}})<({{n}_{1}}+{{n}_{2}})\] eg.          \[{{N}_{2}}+3{{H}_{2}}2N{{H}_{3}}\] then                      \[{{K}_{p}}<{{K}_{c}}\] 3. When \[({{m}_{1}}+{{m}_{2}})=({{n}_{1}}+{{n}_{2}})\] eg,          \[{{H}_{2}}+C{{l}_{2}}2HCl\] then                      \[{{k}_{p}}={{k}_{c}}\]


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