BCECE Medical BCECE Medical Solved Papers-2010

  • question_answer
    A saturated solution of \[A{{g}_{2}}S{{O}_{4}}\] is \[2.5\times {{10}^{-2}}M\]. The value of its solubility product is

    A)  \[62.5\times {{10}^{-6}}\]

    B)  \[6.25\times {{10}^{-4}}\]

    C)  \[15.625\times {{10}^{-6}}\]   

    D)  \[3.125\times {{10}^{-6}}\]

    Correct Answer: A

    Solution :

    Given, solubility of \[A{{g}_{2}}S{{O}_{4}}=2.5\times {{10}^{-2}}M\] Let the solution of \[A{{g}_{2}}S{{O}_{4}}=x\,mol/L\]                 \[A{{g}_{2}}S{{O}_{4}}\xrightarrow{{}}2A{{g}^{+}}+SO_{4}^{2-}\]                 \[\underset{x}{\mathop{A{{g}_{2}}S{{O}_{4}}}}\,\xrightarrow{{}}2A{{g}^{+}}+SO_{4}^{2-}\]                 \[{{K}_{sp=}}{{[A{{g}^{+}}]}^{2x}}{{[SO_{4}^{2-}]}^{x}}\]                 \[={{(2x)}^{2}}(x)\]                 \[=4{{x}^{3}}\]                 \[=4\times {{(2.5\times {{10}^{-2}})}^{3}}\] \[=62.5\times {{10}^{-6}}\]


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