BHU PMT BHU PMT (Mains) Solved Paper-2006

  • question_answer

    Directions : In the following question more than one of the answers given may be correct. Select the correct answer and mark it according to the code:

    Hydroxylamine reacts with: (1)\[C{{H}_{3}}COC{{H}_{3}}\]                    (2)\[C{{H}_{3}}COCl\] (3) \[{{C}_{6}}{{H}_{5}}Cl\]          (4)

    A)  1, 2 and 3 are correct

    B)  1 and 2 are correct

    C)   2 and 4 are correct

    D)  1 and 3 are correct

    Correct Answer: B

    Solution :

                     \[C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-C{{H}_{3}}\xrightarrow[-HCl]{N{{H}_{2}}OH}C{{H}_{3}}-\overset{\begin{smallmatrix}  NOH \\  || \end{smallmatrix}}{\mathop{C}}\,\underset{oxime}{\mathop{-C{{H}_{3}}}}\,\] \[C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-Cl\xrightarrow[-{{C}_{2}}{{H}_{5}}OH]{N{{H}_{2}}OH}\underset{hydroxamic\,acid}{\mathop{C{{H}_{3}}-\overset{\begin{smallmatrix}  O \\  || \end{smallmatrix}}{\mathop{C}}\,-NHOH}}\,\]


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