BHU PMT BHU PMT (Mains) Solved Paper-2007

  • question_answer
    When phosphorus reacts with caustic soda, the products are PH3 and\[Na{{H}_{2}}P{{O}_{2}}\]. This reaction is an example of

    A)  oxidation          

    B)  reduction

    C)  disproportionation        

    D)  none of these

    Correct Answer: C

    Solution :

                     \[{{\overset{0}{\mathop{P}}\,}_{4}}+3NaOH+3{{H}_{2}}O\to \overset{-3}{\mathop{P}}\,{{H}_{3}}+3Na{{H}_{2}}\overset{+1}{\mathop{P}}\,{{O}_{2}}\] Oxidation number of P changes from zero to\[-3\] in\[P{{H}_{3}}\]and +1 in\[Na{{H}_{2}}P{{O}_{2}}\]. Therefore, it is an example of disproportionation reaction.


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