BHU PMT BHU PMT (Mains) Solved Paper-2008

  • question_answer
    Which of the following pairs of a chemical reaction is certain to result in a spontaneous reaction?

    A)  Exothermic and decreasing disorder

    B)  Endothermic and increasing disorder

    C)  Exothermic and increasing disorder

    D)  Endothermic and decreasing disorder

    Correct Answer: C

    Solution :

                     We know that \[\Delta G=\Delta H-T\Delta S\] For exothermic reaction,\[\Delta H=-\text{ }ve\] For endothermic reaction,\[\Delta H=+\text{ }ve\] As disorder increases, \[\Delta S=+\text{ }ve\] As disorder decreases,\[\Delta S=-\text{ }ve\] For a spontaneous reaction\[\Delta G\]must be negative and for negative value of\[\Delta G,\text{ }\Delta H\] must be negative (ie, exothermic reaction) and\[\Delta S\]must be positive (ie, disorder increases) (according to the above equation).


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