BHU PMT BHU PMT (Mains) Solved Paper-2009

  • question_answer
    Acetylene, carbon monoxide and ethyl alcohol react in the presence of nickel catalyst. The product will be

    A)  ester of unsaturated acid

    B)  ester of saturated acid

    C)   R in the\[COOH\]of ester is an unsymmetrical radical

    D)  ester does not form at all

    Correct Answer: A

    Solution :

                     When acetylene reacts with CO and\[{{C}_{2}}{{H}_{5}}OH\]in the presence of Ni, an unsaturated ester is formed. \[HC\equiv CH+CO+{{C}_{2}}{{H}_{5}}OH\xrightarrow[{}]{Ni}\]\[\underset{\begin{smallmatrix}  \,\,\,\,\,\,ethyl\text{ }acrylate \\  (unsaturated\text{ }ester) \end{smallmatrix}}{\mathop{C{{H}_{2}}=CHCOO{{C}_{2}}{{H}_{5}}}}\,\]


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