BHU PMT BHU PMT (Mains) Solved Paper-2011

  • question_answer
    Which of the following relationships is correct?

    A)  \[K=\frac{T\Delta {{S}^{o}}-\Delta {{H}^{o}}}{RT}\]         

    B)  \[K=\frac{\Delta {{H}^{o}}-T\Delta {{S}^{o}}}{RT}\]

    C)  In\[K=\frac{T\Delta {{S}^{o}}-\Delta {{H}^{o}}}{RT}\]     

    D)  In\[K=\frac{\Delta {{H}^{o}}-T\Delta {{S}^{o}}}{RT}\]

    Correct Answer: C

    Solution :

    Sol.         \[\Delta G{}^\circ =-RT\]In K and    \[\Delta G{}^\circ =\Delta {{H}^{o}}-T\Delta {{S}^{o}}\] Hence, \[-RT\]In \[K=\Delta {{H}^{o}}-T.\Delta {{S}^{o}}\] \[RT\,In\,K=T\Delta {{S}^{o}}-\Delta {{H}^{o}}\] \[In\,K=\frac{T\Delta {{S}^{o}}-\Delta {{H}^{o}}}{RT}\]


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