BHU PMT BHU PMT (Mains) Solved Paper-2011

  • question_answer
    Equivalent weight of\[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\]in acidic medium is

    A)  \[M\]                                  

    B)  \[\frac{M}{2}\]

    C)  \[\frac{M}{5}\]                                

    D)  \[\frac{M}{6}\]

    Correct Answer: D

    Solution :

    Sol.         \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}+4{{H}_{2}}S{{O}_{4}}\xrightarrow{{}}\] \[{{K}_{2}}S{{O}_{4}}+C{{r}_{2}}{{(S{{O}_{4}})}_{3}}+4{{H}_{2}}O+3[O]\] or\[C{{r}_{2}}O_{7}^{2-}+14{{H}^{+}}+6{{e}^{-}}\xrightarrow{{}}2C{{r}^{3+}}+7{{H}_{2}}O\] Equivalent weight of \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}=\frac{molecular\text{ }mass}{6}\]


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