BHU PMT BHU PMT (Screening) Solved Paper-2005

  • question_answer
    Which of the following is a chiral carbon?

    A) \[C{{H}_{4}}\]                                   

    B)  \[C{{H}_{3}}I\]

    C)  \[C{{H}_{2}}C{{l}_{2}}\]               

    D)  \[CHIBrCl\]

    Correct Answer: D

    Solution :

                     Key Idea: optically active compound has asymmetric or chiral carbon atom that is a carbon atom attached to four different atoms. \[H-\underset{\begin{smallmatrix}  | \\  H \end{smallmatrix}}{\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}}\,-H\] \[H-\underset{\begin{smallmatrix}  | \\  I \end{smallmatrix}}{\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}}\,-H\] \[\because \]all four atoms         \[\because \]3 atoms attached      attached to                        to carbon are      carbon are same            same \[\therefore \]No chiral carbon                 \[\therefore \]No chiral carbon     present                              present \[Cl-\underset{\begin{smallmatrix}  | \\  Cl \end{smallmatrix}}{\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}}\,-H\] \[Br-\underset{\begin{smallmatrix}  | \\  Cl \end{smallmatrix}}{\overset{\begin{smallmatrix}  H \\  | \end{smallmatrix}}{\mathop{C}}}\,-I\]   \[\because \]2 atoms are identical \[\because \]all 4 atoms attached              to carbon are different \[\therefore \]No chiral carbon       \[\therefore \]chiral carbon present present


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