BHU PMT BHU PMT (Screening) Solved Paper-2005

  • question_answer
    The reaction of\[HBr\]with \[C{{H}_{3}}-\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}\,=C{{H}_{2}}\]in the presence of peroxide will give:

    A)  \[\underset{\begin{smallmatrix}  | \\  C{{H}_{3}} \end{smallmatrix}}{\mathop{C{{H}_{3}}CBrC{{H}_{3}}}}\,\]         

    B)  \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}Br\]

    C)  \[\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C{{H}_{3}}CHC{{H}_{2}}Br}}\,\]      

    D)  \[\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C{{H}_{3}}C{{H}_{2}}CHC{{H}_{3}}}}\,\]

    Correct Answer: C

    Solution :

                     Key Idea: The reaction with\[HBr\]follows anti- Markownikoff rule. The rule states that negative part of adding reagent goes to carbon atom having more number of hydrogen atoms. \[C{{H}_{3}}-\overset{\begin{smallmatrix}  C{{H}_{3}} \\  | \end{smallmatrix}}{\mathop{C}}\,=C{{H}_{2}}+HBr\xrightarrow[{}]{Peroxide}\]


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