BHU PMT BHU PMT (Screening) Solved Paper-2009

  • question_answer
    Which of the following reagents can be used for distinguishing the three classes of alcohols?

    A)  Fenton's reagent

    B)  Lucas reagent

    C)   Schiff?s reagent

    D)  Tollen?s reagent

    Correct Answer: B

    Solution :

                     Lucas reagent can be used for distinguishing the primary, secondary and tertiary alcohols. Lucas reagent is a mixture of cone\[HCl\]and anhydrous\[ZnC{{l}_{2}}\]. \[Tertiary\text{ }alcohol\xrightarrow[reagent]{Lucas}reacts\text{ }immediately\]forming an oily layer in cold. \[Secondary\text{ }alcohol\xrightarrow[reagent]{Lucas}reacts\text{ }within\]5-10 min \[Primary\text{ }alcohol\xrightarrow[reagent]{Lucas}does\text{ }not\text{ }react\]appreciably in cold.


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