BVP Medical BVP Medical Solved Paper-2002

  • question_answer
    Heat of combustion of C, S and \[C{{S}_{2}}\] are \[-393.3,-293.72\]and\[-1108.76\text{ }kJ/mole\]. The heat of formation of \[C{{S}_{2}}\] will be:

    A)  \[+128.02\text{ }kJ\]                    

    B)  \[-128.02kJ\]

    C)  \[-212.24\text{ }kJ\]     

    D)  \[+212.24\text{ }kJ\]

    Correct Answer: A

    Solution :

                    Given, \[C+{{O}_{2}}\xrightarrow{{}}C{{O}_{2}},\Delta H=-393.3kJ\]?..(i) \[S+{{O}_{2}}\xrightarrow{{}}S{{O}_{2}},\,\Delta H=-293.72kJ\]?..(ii) \[C{{S}_{2}}+3{{O}_{2}}\xrightarrow{{}}C{{O}_{2}}+2S{{O}_{2}},\], \[\Delta H=-1108.76kJ\]        ?..(iii) Required equation is                 \[C+2S\xrightarrow{{}}C{{S}_{2}},\,\,\Delta H=?\]                 \[\frac{Eq\,(i)+2\times Eq(ii)-Eq(iii)}{C+2S-C{{S}_{2}}}\]                 \[\Delta H=128.02kJ\]


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