BVP Medical BVP Medical Solved Paper-2003

  • question_answer
    Addition of \[SnC{{l}_{2}}\] to \[HgC{{l}_{2}}\] gives ppt:

    A)  white turning to red

    B)  white turning to grey

    C)  black fuming to white

    D)  none

    Correct Answer: B

    Solution :

                    Stannous chloride \[(SnC{{l}_{2}})\] is a good reducing agent. It reduces \[HgC{{l}_{2}}\] into \[Hg\] (grey precipitate), in two steps. \[SnC{{l}_{2}}+2HgC{{l}_{2}}\xrightarrow{{}}SnC{{l}_{4}}+\underset{white}{\mathop{HgC{{l}_{2}}}}\,\downarrow \] \[SnC{{l}_{2}}+H{{g}_{2}}C{{l}_{2}}\xrightarrow{{}}SnC{{l}_{4}}+\underset{grey}{\mathop{2Hg}}\,\downarrow \]


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