BVP Medical BVP Medical Solved Paper-2004

  • question_answer
    Solubility of \[Pb{{I}_{2}}\]. is 0.005 M. Then, the solubility product of \[Pb{{I}_{2}}\] is:

    A)  \[6.8\times {{10}^{-6}}\]             

    B)  \[6.8\times {{10}^{6}}\]

    C)  \[2.2\times {{10}^{-9}}\]             

    D)  none of these

    Correct Answer: D

    Solution :

    \[\underset{s\,\,mol/litre}{\mathop{Pb{{I}_{2}}}}\,\underset{s}{\mathop{P{{b}^{2+}}}}\,+\underset{2s}{\mathop{2{{I}^{-}}}}\,\] \[\therefore \]   \[{{K}_{sp}}=[P{{b}^{2+}}]{{[{{I}^{-}}]}^{2}}\]                 \[=(s){{(2s)}^{2}}\]                 \[=4{{s}^{3}}\] Given, that s = 0.005 mot/litre \[\therefore \]  \[{{K}_{sp}}=4{{(0.005)}^{3}}\]                 \[=5.00\times {{10}^{-7}}\]


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