BVP Medical BVP Medical Solved Paper-2004

  • question_answer
    What is obtained, when acetic acid is heated with chlorine in presence of red phosphorus?

    A)  Acetyl chloride

    B)  a-chloro acetic acid

    C)  Trichloro acetic acid

    D)  Chloral

    Correct Answer: B

    Solution :

                    In presence of red phosphorus, acids give a-substituted acids, on heating. It is called Hell-Volhard Zclinsky reaction (HVZ). \[\underset{\alpha -chloro\,acrtic\,acid}{\mathop{C{{H}_{3}}COOH\xrightarrow[\operatorname{Re}d.P]{C{{l}_{2}}}\overset{Cl}{\mathop{\overset{|}{\mathop{C{{H}_{2}}}}\,}}\,-COOH}}\,\]


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