A) \[C{{H}_{3}}Cl\]
B) \[C{{H}_{3}}C{{H}_{2}}Cl\]
C) \[{{(C{{H}_{3}})}_{3}}CCl\]
D) \[C{{H}_{2}}=CH-Cl\]
Correct Answer: D
Solution :
\[C{{H}_{2}}=CH-Cl\] is least reactive with the hydrolysis point of view because vinylic halides do not undergo \[{{S}_{N}}1\] reaction due to instability of their carbocations. The \[Cl-Cl\] bond is stronger and therefore, formation carbocation is difficult.
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