BVP Medical BVP Medical Solved Paper-2014

  • question_answer
    For    \[-76\,kJ\,mo{{r}^{-1}}\] at equilibrium \[5mL\] and p is the total pressure, the ratio \[A{{s}_{2}}{{S}_{3}}\] will be

    A)  \[2Ag+2HCl+(O)\xrightarrow{{}}2AgCl+{{H}_{2}}O\]                                      

    B)  \[N{{i}_{2}}{{O}_{2}}(s)+{{H}_{2}}O(l)+2{{e}^{-}}2NiO(s)+2O{{H}^{-}}\]

    C)  \[{{E}^{o}}=+0.40V\]                                    

    D)  \[FeO(s)+{{H}_{2}}O(l)+2{{e}^{-}}Fe(s)+2O{{H}^{-}};\]

    Correct Answer: C

    Solution :

                    \[\underset{\begin{smallmatrix}  p-\left( \frac{2p}{9}+\frac{p}{9} \right) \\  =\frac{6p}{9} \end{smallmatrix}}{\mathop{2NOBr(g)}}\,\underset{\frac{2p}{9}}{\mathop{2NO(g)}}\,+\underset{\frac{p}{9}}{\mathop{B{{r}_{2}}(g)}}\,\] From     \[{{K}_{p}}=\frac{{{({{p}_{No}})}^{2}}\times ({{p}_{B{{r}_{2}}}})}{{{({{p}_{NOBr}})}^{2}}}\]                 \[=\frac{{{\left( \frac{2p}{9} \right)}^{2}}\left( \frac{p}{9} \right)}{{{\left( \frac{6p}{9} \right)}^{2}}}=\frac{p}{81}\] \[\therefore \]  \[\frac{{{K}_{p}}}{p}=\frac{1}{81}\]


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