CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2000

  • question_answer
    The reaction\[2{{H}_{2}}{{O}_{2}}\xrightarrow{{}}2{{H}_{2}}O+{{O}_{2}}\]is:

    A)  a redox reaction

    B)  a hydrolysis reaction

    C)  a solvolysis reaction

    D)  an oscillatory reaction

    E)  disproportionation

    Correct Answer: E

    Solution :

    \[\underset{+1-1}{\mathop{{{H}_{2}}{{O}_{2}}}}\,+\underset{+1-1}{\mathop{{{H}_{2}}{{O}_{2}}}}\,\xrightarrow{{}}2\underset{+1-2}{\mathop{{{H}_{2}}O}}\,+\underset{0}{\mathop{{{O}_{2}}}}\,\] Here the oxidation number of hydrogen is not changed while the oxidation number of oxygen in\[{{H}_{2}}{{O}_{2}},{{H}_{2}}O\]and\[{{O}_{2}}\]is\[-1,-2\]and 0. Hence, oxygen in undergoing oxidation to\[{{O}_{2}}\](\[-1\]to 0) as well as reduction to\[{{H}_{2}}O(-1\text{ }to-2)\]. Such reactions where a molecule acts as both oxidising and reducing agent are called disproportionation.


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