CEE Kerala Engineering CEE Kerala Engineering Solved Paper-2001

  • question_answer
    The activation energy of a reaction can be determined by:

    A) changing the concentration of the reactants

    B) evaluating the rate constant at standard temperature

    C) evaluating the rate constant at two different concentrations

    D) evaluating the rate constant at two different temperatures

    E) by doubling the concentrations of the reactants

    Correct Answer: D

    Solution :

    The activation energy of a reaction can be determined by evaluating the rate constant at two different temperatures. By knowing the values of rate constant (\[{{K}_{1}}\]and\[{{K}_{2}}\])of the reaction at temperatures\[{{T}_{1}}\]and \[{{T}_{2}}\]respectively, the value of activation energy \[({{E}_{a}})\]can be calculated with the help of following equation. \[\log \frac{{{K}_{2}}}{{{K}_{1}}}=\frac{{{E}_{a}}}{2.303R}\left[ \frac{1}{{{T}_{1}}}-\frac{1}{{{T}_{2}}} \right]\]


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